新賽季歐冠小組賽首輪戰罷 ，欧冠歐足聯也根據球員的首轮發揮公布了本周歐冠最佳陣容 。梅西與C羅兩位頂級巨星所在的最佳阵容球隊都沒有獲得勝利 ，而兩人也都沒有進入最佳陣容。出炉阿賈克斯成為最大的阿贾贏家 ，多內的大赢阿萊以及安東尼成功入選 ，也是家莱入選首輪最佳最多的球隊 。
門將位置上 ，欧冠米蘭的首轮邁尼昂撲出了薩拉赫的點球 ，同時這位門將在對戰利物浦的最佳阵容比賽中有6次成功的撲救 ，因此力壓5次撲救的出炉庫爾圖瓦入選最佳陣容 。後衛位置上，阿贾桑德羅 、大赢坎塞洛 、家莱奧塔門迪以及克裏斯蒂亞諾成功入選 。欧冠其中桑德羅與坎塞洛本輪比賽都打入了進球 ，幫助各自球隊取得大勝 。
中場位置上 ，利物浦的亨德森 、多特蒙德的貝林厄姆以及萊比錫紅牛的恩庫盧入選最佳陣容 。亨德森在與米蘭的比賽下半場打入致勝進球，他的進球直接幫助紅軍在主場3-2獲勝 。多特蒙德的貝林厄姆在同貝西克塔斯的比賽中傳射建功 。萊比錫雖然3-6不敵曼城，但恩昆庫在比賽中上演了帽子戲法 。
前鋒線 ，入選的分別是阿賈克斯的安東尼 、阿萊以及來自拜仁的萊萬 。阿賈克斯在歐冠首輪比賽客場5-1擊敗了葡萄牙體育 ，阿萊在這場比賽中發揮神勇 ，打入四個進球 ，成為球隊贏球最大的功臣 。而他的隊友安東尼在比賽中送出2次助攻 。在拜仁3-0擊敗巴薩的比賽中 ，萊萬繼續強勢表現 ，打進2球 。
歐冠首輪最佳陣容
門將 ：邁尼昂(AC米蘭)
後衛 ：坎塞洛(曼城) 、奧塔門迪(本菲卡) 、克裏斯蒂亞諾(謝裏夫) 、阿萊士-桑德羅(尤文圖斯)
中場 ：亨德森(利物浦) 、貝林厄姆(多特蒙德) 、恩昆庫(RB萊比錫)
前鋒 ：安東尼(阿賈克斯) 、萊萬多夫斯基(拜仁慕尼黑)、阿萊(阿賈克斯)
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